Optimizing bone and biomass co-torrefaction parameters: High-performance arsenic removal from wastewater via co-torrefied bone char.

This study aimed to investigate bone char's physicochemical transformations through co-torrefaction and co-pyrolysis processes with biomass. Additionally, it aimed to analyze the carbon sequestration process during co-torrefaction of bone and biomass and optimize the process parameters of co-torrefaction. Finally, the study sought to evaluate the arsenic sorption capacity of both torrefied and co-torrefied bone char. Bone and biomass co-torrefaction was conducted at 175 °C-300 °C. An orthogonal array of Taguchi techniques and artificial neural networks (ANN) were employed to investigate the influence of various torrefaction parameters on carbon dioxide sequestration within torrefied bone char. A co-torrefied bone char, torrefied at a reaction temperature of 300 °C, a heating rate of 15 °C·min-1, and mixed with 5 g m of biomass (wood dust), was selected for the arsenic (III) sorption experiment due to its elevated carbonate content. The results revealed a higher carbonate fraction (21%) in co-torrefied bone char at 300 °C compared to co-pyrolyzed bone char (500-700 °C). Taguchi and artificial neural network (ANN) analyses indicated that the relative impact of process factors on carbonate substitution in bone char followed the order of co-torrefaction temperature (38.8%) > heating rate (31.06%) > addition of wood biomass (30.1%). Co-torrefied bone chars at 300 °C exhibited a sorption capacity of approximately 3 mg g-1, surpassing values observed for pyrolyzed bone chars at 900 °C in the literature. The findings suggest that co-torrefied bone char could serve effectively as a sorbent in filters for wastewater treatment and potentially fulfill roles such as a remediation agent, pH stabilizer, or valuable source of biofertilizer in agricultural applications.

Thermochemical conversion of silkworm by-product into syngas.

This study explored the valorisation of silkworm by-product, a major by-product of the silk industry (sericulture), which amounts to 16 million tonnes annually. The focus was on transforming waste into energy resources through pyrolysis under CO2 conditions. In one-stage pyrolysis, the evolution of syngas under N2 was found to be comparable to that under CO2. A notable allocation of carbon to biocrude rather than syngas was observed. The two-stage pyrolysis resulted in increased syngas production. However, achieving a homogeneous reaction between CO2 and the volatiles liberated from silkworm byproduct proved challenging. Indeed, the reaction kinetics governing CO2 reactivity was not fast although the temperature windows of the reaction were aligned in the two-stage pyrolysis. To address this issue, pyrolysis was performed using a Ni-based catalyst to expedite the reaction kinetics. Consequently, syngas formation, particularly CO formation, was significantly enhanced under CO2 conditions compared to that under N2 conditions. The syngas yield under CO2 was 36.42 wt% which was 2-fold higher than that of N2. This suggested the potential of CO2 altering the carbon distribution from biocrude to syngas. This strategy would contribute to the establishment of sustainable production of silk by converting sericulture by-product into energy/chemical resources.

Effects of water washing and KOH activation for upgrading microalgal torrefied biochar.

Torrefaction is an effective pathway for microalgal solid biofuel upgrading, and alkali metal activation is also an efficient method to enhance fuel properties. This study explores the comparison of torrefaction alone and KOH activation combined with torrefaction to determine a better operation for biochar production from the microalga Nannochloropsis Oceanica. The results indicate that the HHV ranges of KOH-activated biochar and unactivated biochar are 25.611-32.792 MJ·kg-1 and 25.024-26.389 MJ·kg-1, respectively. Furthermore, KOH-activated biochar is better than unactivated biochar, with less residue, broader pyrolysis and combustion temperature ranges, higher elemental carbon, and less combined carbon. Moreover, KOH-activated biochar is close to the unactivated one from the viewpoint of expense calculation and life cycle assessment and thus possesses a better comprehensive performance. Overall, KOH activation is an efficient method for upgrading microalgal solid biofuel. The results are conducive to exploring further modification of microalgal solid biofuel production with better properties, thus leading to a greener and more efficient approach for upgrading fuel performance.

Developing a sorptive material of cadmium from pyrolysis of hen manure.

A large amount of manure is generated from concentrated animal feeding operations (CAFOs), leading to serious environmental issues and hazardous risks from pathogens, such as methicillin-resistant Staphylococcus aureus. Therefore, developing an effective method for manure disposal is essential. Thus, in this study, we suggest the use of CO2 in pyrolysis of hen manure (HM) as an effective method to convert the carbon in HM into syngas (especially carbon monoxide (CO)). HM was used and tested as the model compound. From the results of thermo-gravimetric analysis, the decarboxylation of CaCO3 in HM in the presence of N2 was realized at temperatures ranging from 638 to 754 °C. The Boudouard reaction was observed at ≥ 664 °C in the presence of CO2. Despite the lack of occurrence of the Boudouard reaction, more CO formation was observed in the presence of CO2 at ≥ 460 °C. This was deemed as a homogeneous reaction induced by CO2. Considering the high Ca content of HM, HM biochar in N2 and CO2 were used as adsorbent for removal of Cadmium (Cd), which is toxic heavy metal. The adsorption capacities of HM_N2 and HM_CO2 were 302.4 and 95.7 mg g-1, respectively. The superior performance of HM_N2 is mainly attributed to the presence of Ca(OH)2, which provides favorable (alkaline) conditions for precipitation and ion exchange. Our results indicate the environmental benefits from using CO2. Specifically, CO2 (representative greenhouse gas) converted into fuel. Given this, pyrolysis of HM in the presence of CO2 was achieved at ≤ 640 °C, and the atmospheric condition should be switched from CO2 to N2 at ≥ 640 °C to ensure the decarboxylation of CaCO3.

Direct conversion of apricot seeds into biodiesel.

Using edible lipids for biodiesel production has been criticized, causing biodiesel production from inedible food resources to be desirable. Lipid extraction must be prioritized to produce biodiesel using an acid/base-catalyzed transesterification process, but this conversion process suffers from technical reliability. Therefore, this study introduced non-catalytic conversion of oil-bearing biomass into biodiesel. Apricot seeds were used as a model compound (oil content 44.3 wt%). The non-catalytic transesterification of apricot seed oil recovered 98.28 wt% biodiesel at 360 °C for 1 min, while alkali-catalysis of apricot seed oil recovered 91.84 wt% at 63 °C for 60 min. The direct conversion of apricot seeds into biodiesel was attempted. The trends in the yields of biodiesel from apricot seeds and seed oil obtained by non-catalytic transesterification as a function of reaction temperature were similar. The yield of biodiesel from apricot seed was 43.06 wt%, suggesting that 97.20 wt% of lipids were converted into biodiesel.

Advancements in TiO2-based photocatalysis for environmental remediation: Strategies for enhancing visible-light-driven activity.

Researchers have focused on efficient techniques for degrading hazardous organic pollutants due to their negative impacts on ecological systems, necessitating immediate remediation. Specifically, TiO2-based photocatalysts, a wide-bandgap semiconductor material, have been extensively studied for their application in environmental remediation. However, the extensive band gap energy and speedy reattachment of electron (e-) and hole (h+) pairs in bare TiO2 are considered major disadvantages for photocatalysis. This review extensively focuses on the combination of semiconducting photocatalysts for commercial outcomes to develop efficient heterojunctions with high photocatalytic activity by minimizing the e-/h+ recombination rate. The improved activity of these heterojunctions is due to their greater surface area, rich active sites, narrow band gap, and high light-harvesting tendency. In this context, strategies for increasing visible light activity, including doping with metals and non-metals, surface modifications, morphology control, composite formation, heterojunction formation, bandgap engineering, surface plasmon resonance, and optimizing reaction conditions are discussed. Furthermore, this review critically assesses the latest developments in TiO2 photocatalysts for the efficient decomposition of various organic contaminants from wastewater, such as pharmaceutical waste, dyes, pesticides, aromatic hydrocarbons, and halo compounds. This review implies that doping is an effective, economical, and simple process for TiO2 nanostructures and that a heterogeneous photocatalytic mechanism is an eco-friendly substitute for the removal of various pollutants. This review provides valuable insights for researchers involved in the development of efficient photocatalysts for environmental remediation.

Strategic use of crop residue biochars for removal of hazardous compounds in wastewater.

Crop residues are affordable lignocellulosic waste in the world, and a large portion of the waste has been burned, releasing toxic pollutants into the environment. Since the crop residue is a carbon and ingredient rich material, it can be strategically used as a sorptive material for (in)organic pollutants in the wastewater after thermo-chemical valorization (i.e., biochar production). In this review, applications of crop residue biochars to adsorption of non-degradable synthetic dyes, antibiotics, herbicides, and inorganic heavy metals in wastewater were discussed. Properties (porosity, functional groups, heteroatom, and metal(oxide)s, etc.) and adsorption capacity relationships were comprehensively reviewed. The current challenges of crop residue biochars and guidelines for development of efficient adsorbents were also provided. In the last part, the future research directions for practical applications of the crop residue biochars in wastewater treatment plants have been suggested.

Multistage utilization of soybean straw-derived P-doped biochar for aquatic pollutant removal and biofuel usage.

Biochar is of great importance to realizing solid biowastes reduction and environmental remediation. Modifying biochar for better performance is also of great concern to achieve property improvement. P-doped biochar from soybean straw is prepared for multistage utilization to realize water pollutant removal and biofuel usage. The results suggest that the prepared biochar is adequate for sulfadiazine adsorption and has stable performance under coexisting ions and aquatic pH. Furthermore, the higher heating value of the biochar is close to coal and thus can be an alternative to fossil fuel. The maximum sulfadiazine adsorption amount of P-doped biochar is 252.24 mg·g-1, and the P-doped biochar HHV is 24 MJ·kg-1 which can be an alternative to coal. The greenhouse gas and pollutant emission potential are also considered to explore the environmental impact of P-doped biochar production and usage. Overall, the optimal ratio of soybean straw: K3PO4 is 3:1.

A critical review on biochar production from pine wastes, upgradation techniques, environmental sustainability, and challenges.

Pine wastes, including pine needles, cones, and wood, are abundantly produced as an agroforestry by-product globally and have shown tremendous potential for biochar production. Various thermochemical conversion technologies have exhibited promising results in converting pine wastes to biochar, displaying impressive performance. Hence, this review paper aims to investigate the possibilities and recent technological advancements for synthesizing biochar from pine waste. Furthermore, it explores techniques for enhancing the properties of biochar and its integrated applications in various fields, such as soil and water remediation, carbon sequestration, battery capacitor synthesis, and bio-coal production. Finally, the paper sheds light on the limitations of current strategies, emphasizing the need for further research and study to address the challenges in pine waste-based biochar synthesis. By promoting sustainable and effective utilization of pine wastes, this review contributes to environmental conservation and resource management.

Low-temperature biochar production from torrefaction for wastewater treatment: A review.

Biochar, a carbon-rich and por ous material derived from waste biomass resources, has demonstrated tremendous potential in wastewater treatment. Torrefaction technology offers a favorable low-temperature biochar production method, and torrefied biochar can be used not only as a solid biofuel but also as a pollutant adsorbent. This review compares torrefaction technology with other thermochemical processes and discusses recent advancements in torrefaction techniques. Additionally, the applications of torrefied biochar in wastewater treatment (dyes, oil spills, heavy metals, and emerging pollutants) are comprehensively explored. Many studies have shown that high productivity, high survival of oxygen-containing functional groups, low temperature, and low energy consumption of dried biochar production make it attractive as an adsorbent for wastewater treatment. Moreover, used biochar's treatment, reuse, and safe disposal are introduced, providing valuable insights and contributions to developing sustainable environmental remediation strategies by biochar.

Hollow-Structured N-doped carbon-embedded CoFe NanoAlloy for boosting activation of Monopersulfate: Engineered interface and heteroatom Doping-Induced enhancements.

While transition metals are useful for activating monopersulfate (MPS) to degrade contaminants, bimetallic alloys exhibit stronger catalytic activities owing to several favorable effects. Therefore, even though Co is an efficient metal for MPS activation, CoFe alloys are even more promising heterogeneous catalysts for MPS activation. Immobilization/embedment of CoFe alloy nanoparticles (NPs) onto hetero-atom-doped carbon matrices appears as a practical strategy for evenly dispersing CoFe NPs and enhancing catalytic activities via interfacial synergies between CoFe and carbon. Herein, N-doped carbon-embedded CoFe alloy (NCCF) is fabricated here to exhibit a unique hollow-engineered nanostructure and the composition of CoFe alloy by using Co-ZIF as a precursor after the facile etching and Fe doping. The Fe dopant embeds CoFe alloy NPs into the hollow-structured N-doped carbon substrate, enabling NCCF to possess the higher mesoscale porosity, active N species as well as more superior electrochemical properties than its analogue without Fe dopants, carbon matrix-supported cobalt (NCCo). Thus, NCCF exhibits a considerably larger activity than NCCo and the benchmark catalyst, Co3O4 NP, for MPS activation to degrade an environmental hormone, dihydroxydiphenyl ketone (DHPK). Besides, NCCF + MPS shows an even lower activation energy for DHPK degradation than literatures, and retains its high efficiency for eliminating DHPK in different water media. DHPK degradation pathway and ecotoxicity assessment are unraveled based on the insights from the computational chemistry, demonstrating that DHPK degradation by NCCF + MPS did not result in the formation of toxic and highly toxic by-products. These features make NCCF a promising heterogeneous catalyst for MPS activation to degrade DHPK.

Abatement of odor emissions from wastewater treatment plants using biochar.

Odor is a critical environmental problem that negatively affects people's quality of life. Wastewater treatment plants (WWTPs) often emit various odorous compounds, such as ammonia, sulfur dioxide, and organosulfur. Abatement of odor emissions from WWTPs using biochar may contribute to achieving carbon neutrality due to the carbon negative nature, CO2 sorption, and negative priming effects of biochar. Biochar has a high specific surface area and microporous structure with appropriate activation, which is suitable for sorption purposes. Various research directions have been proposed to determine the biochar removal efficiency for different odorants released from WWTPs. According to the literature survey, the pre- and post-treatments (e.g., thermal treatment, chemical treatment, and metal impregnation) of biochar could enhance the removal capacity for the odorants emitted from WWTPs at comparable conditions, compared to unmodified biochar. The feedstock and production condition (particularly, pyrolysis temperature) of a biochar and initial concentration of an odorant markedly affect the biochar's odorant removal capacity and efficiency. Moreover, different adsorption systems for the removal of odorants emitted from WWTPs follow different adsorption models. Further research is required to establish the practical use of biochar for the mitigation of odors released from WWTPs.

Construction and demolition waste as a high-efficiency advanced process for organic pollutant degradation in Fenton-like reaction to approach circular economy.

The Fenton-like reaction is a promising organic wastewater treatment reaction among advanced oxidation processes (AOP), which has emerged to replace the conventional Fenton reaction. Recycled construction and demolition waste (CDW), which is porous and rich in iron, manganese, and magnesium, can be reused as a Fenton-like catalyst. This study proposes an AOP wastewater treatment strategy using recycled porous CDW mixed with hydrogen peroxide (H2O2) to decompose methylene blue (MB) wastewater. According to the apparent first-order rate (Kapp) of 10 ppm MB adsorption, CDW-3, having the highest specific surface area, also has the highest Kapp of 0.23 min-1 g-1. The optimized conditions recommended by the Taguchi method include a 0.3 g mL-1 CDW-3 concentration, a 0.254 g mL-1 H2O2 concentration, and 10 ppm MB, resulting in an about 2.01 min-1Kapp value. In addition, MB concentration is observed as the most influential factor for Kapp, which decreases with increasing MB concentration and is about 0.62 min-1 at 1000 ppm MB. Repeating the Fenton-like reaction five times at 100 p.m. MB using the same CDW-3, the Kapp is about 0.64 min-1, which is 86% of the initial run. The synergistic effect index (ξ) is defined to quantify the level of interaction between CDW and H2O2, which produces free radicals during the Fenton-like process. The ξ of CDW-3 is about 2.16. Overall, it is demonstrated that CDW is a promising catalyst for Fenton-like reactions, and the synergistic effect index (ξ) can be used as a reference index to evaluate the catalytic generation of free radicals between the catalyst and H2O2.

Quantitative analysis of polystyrene microplastic and styrene monomer released from plastic food containers.

Since the COVID-19 outbreak, the use of disposable plastics has rapidly increased along with the amount of plastic waste. During fragmentation, microplastics and other chemical substances contained in plastics are released. These then enter humans through food which could be problematic considering their hazardous potential. Polystyrene (PS), which is widely used in disposable containers, releases large amounts of microplastics (MPs), but no studies have investigated the release mechanisms of PS-MPs and simultaneously exposed contaminants. Therefore, in this study, the effects of pH (3, 5, 7, and 9), temperature (20, 50, 80, and 100 °C), and exposure time (2, 4, 6, and 8 h) on MPs release were systematically examined. A quantitative/qualitative study of MPs and styrene monomers was performed using microscopy-equipped Fourier-transformed infrared spectroscopy and gas chromatography-mass spectrometry. The release of PS-MPs (36 items/container) and simultaneously exposed pollutants (SEP), such as ethylene glycol monooleate (EGM), was highest at pH 9, 100 °C, and 6 h, which was proportional to the test temperature and time. Under the same conditions, 2.58 µg/L of styrene monomer migrated to the liquid food simulants. The fragmentation was proceeded by oxidation/hydrolysis and accelerated by increased temperature and exposure time. The strong positive correlation between PS-MPs and SEPs releases at pH and temperature indicates that PS-MPs and SEPs follow the same release process. However, a strongly negative correlation between PS-MPs and styrene monomers at the exposed time shows that styrene migration does not follow the same release process, but does its partition coefficient.

Selective recovery of caprolactam from the thermo-catalytic conversion of textile waste over γ-Al2O3 supported metal catalysts.

The massive generation of synthetic textile waste has drawn considerable attention. Landfilling/incineration of textile waste has been widely made. To abate the environmental burdensome from the conventional management processes, a thermo-catalytic conversion was used for rapid volume reduction of textile waste and simultaneous valorization by recovering textile monomer in this study. Stockings were chosen as a model feedstock. Because stockings consisted of nylon with other contents, different products (caprolactam (nylon monomer), imines, cyclic dimers, and azepines) were recovered. The yield of caprolactam from the thermal conversion at 500 °C was 53.6 wt%. To selectively enhance the caprolactam yield, catalytic pyrolysis was done using γ-Al2O3 supported metal catalysts (Ni, Cu, Fe, or Co). γ-Al2O3 itself increased the caprolactam yield up to 69.0 wt% via a based-catalyzed reaction of nylon depolymerization and intramolecular cyclization. Under the presence of metal catalysts, the caprolactam yield increased up to 73.3 wt%. To offer desired feature of green chemistry, CO2 was adopted as reactive gas. Under the CO2-mediated catalytic pyrolysis, caprolactam yield was enhanced up to 77.1 wt% over Cu/Al2O3 (basis: stocking mass). Based on the net content of nylon in the stockings, the yield of caprolactam was deemed 95.3 wt%. This study proves that textile waste (stocking) and CO2 are useful resources for recovery of nylon monomer, which can reduce the waste generation with simultaneous recovery of value-added product.

Boosting elimination of sunscreen, Tetrahydroxybenzophenone (BP-2), from water using monopersulfate activated by thorny NanoBox of Co@C prepared via the engineered etching strategy: A comparative and mechanistic investigation.

As sunscreens, benzophenones (BPs), are regarded as emerging contaminants, most of studies are focused on removal of 2-hydroxy-4-methoxybenzophenone (BP-3), which, however, has been employed for protecting skin. Another major class of BPs, which is used to prevent UV-induce degradation in various products, is completely neglected. Thus, this present study aims to develop a useful advanced oxidation process (AOP) for the first time to eliminate such a class of BP sunscreens from contaminated water. Specifically, 2,2',4,4'-Tetrahydroxybenzophenone (BP-2) would be focused here as BP-2 is intensively used in perfumes, lipsticks, and plastics for preventing the UV-induced degradation. As monopersulfate (MPS)-based AOP is practical for degrading emerging contaminants, a facile nanostructured cobalt-based material is then developed for maximizing catalytic activities of MPS activation by immobilizing Co nanoparticles onto carbon substrates. In particular, ZIF-67 is employed as a template, followed by the etching and carbonization treatments to afford the thorny nanobox of Co@C (TNBCC) with the hollow-nanostructure. In comparison to the solid (non-hollow) nanocube of Co@C (NCCC) from the direct carbonization of ZIF-67, TNBCC possesses not only the excellent textural features, but also superior electrochemical properties and highly reactive surfaces, making TNBCC exhibit the significantly higher catalytic activity than NCCC as well as Co3O4 in activating MPS to degrade BP-2. Mechanisms of BP-2 degradation are also elucidated and ascribed to both radical and non-radical routes. These advantageous features make TNBCC a useful catalyst of activating MPS in BP-2 degradation.

Direct growth of nano-worm-like Cu2S on copper mesh as a hierarchical 3D catalyst for Fenton-like degradation of an imidazolium room-temperature ionic liquid in water.

The increasing consumption of room-temperature ionic liquids (RTILs) inevitably releases RTILs into the water environment, posing serious threats to aquatic ecology due to the toxicities of RTILs. Thus, urgent needs are necessitated for developing useful processes for removing RTILs from water, and 1-butyl-3-methylimidazolium chloride (C4mimCl), the most common RTIL, would be the most representative RTIL for studying the removal of RTILs from water. As advanced oxidation processes with hydrogen peroxide (HP) are validated as useful approaches for eliminating emerging contaminants, developing advantageous heterogeneous catalysts for activating HP is the key to the successful degradation of C4mim. Herein, a hierarchical structure is fabricated by growing Cu2S on copper mesh (CSCM) utilizing CM as a Cu source. Compared to its precursor, CuO@CM, this CSCM exhibited tremendously higher catalytic activity for catalyzing HP to degrade C4mim efficiently because CSCM exhibits much more superior electrochemical properties and reactive sites, allowing CSCM to degrade C4mim rapidly. CSCM also exhibits a smaller Ea of C4mim elimination than all values in the literature. CSCM also shows a high capacity and stability for activating HP to degrade C4mim in the presence of NaCl and seawater. Besides, the mechanistic investigation of C4mim elimination by CSCM-activated HP has also been clarified and ascribed to OH and 1O2. The elimination route could also be examined and disclosed in detail through the quantum computational chemistry, confirming that CSCM is a useful catalyst for catalyzing HP to degrade RTILs.

Applications of agricultural residue biochars to removal of toxic gases emitted from chemical plants: A review.

Crop residues are representative agricultural waste materials, massively generated in the world. However, a large fraction of them is currently being wasted, though they have a high potential to be used as a value-added carbon-rich material. Also, the applications of carbon-rich materials from agricultural waste to industries can have economic benefit because waste-derived carbon materials are considered inexpensive waste materials. In this review, valorization methods for crop residues as carbon-rich materials (i.e., biochars) and their applications to industrial toxic gas removals are discussed. Applications of crop residue biochars to toxic gas removal can have significant environmental benefits and economic feasibility. As such, this review discussed the technical advantages of the use of crop residue biochars as adsorbents for hazardous gaseous pollutants and greenhouse gases (GHGs) stemmed from combustion of fossil fuels and the different refinery processes. Also, the practical benefits from the activation methods in line with the biochar properties were comprehensively discussed. The relationships between the physico-chemical properties of biochars and the removal mechanisms of gaseous pollutants (H2S, SO2, Hg0, and CO2) on biochars were also highlighted in this review study. Porosity controls using physical and chemical activations along with the addition of specific functional groups and metals on biochars have significantly contributed to the enhancement of flue gas adsorption. The adsorption capacity of biochar for each toxic chemical was in the range of 46-76 mg g-1 for H2S, 40-182 mg g-1 for SO2, 80-952 µg g-1 for Hg0, and 82-308 mg g-1 CO2, respectively. This helps to find suitable activation methods for adsorption of the target pollutants. In the last part, the benefits from the use of biochars and the research directions were prospectively provided to make crop residue biochars more practical materials in adsorption of pollutant gases.

Thermochemical conversion of large-size woody biomass for carbon neutrality: Principles, applications, and issues.

Large-size woody biomass is a valuable renewable resource to replace fossil fuels in biorefinery processes. The preprocessing of wood chips and briquettes is challenging to manage, especially in an industrial setting, as it generates a significant amount of dust and noise and occasionally causes unexpected accidents. As a result, a substantial amount of resources, energy, labor, and space are needed. The thermochemical conversion behavior of large-size woody biomass was studied to reduce energy consumption for chipping. Large-size wood was 1.5 m in length, 0.1 m in breadth, and stacked 90 cm in height. This strategy has many benefits, including increased effectiveness and reduced CO2 emissions. The target of this paper presents the thermochemical process, and large-size wood was chosen because it provides high-quality product gas while reducing the preprocessing fuel cost. This review examines the benefits of thermochemical conversion technologies for assessing the likelihood of carbon neutrality.

Environmental benefits from the use of CO2 in the thermal disposal of cigarette butts.

As the global consumption of cigarettes has increased, the massive generation of cigarette butts (CBs) has led to critical environmental and health problems. Landfilling or incineration of CBs has been conventionally carried out, but such disposal protocols have suffered from the potential risks of the unwanted/uncontrolled release of leachates, carcinogens, and toxic chemicals into all environmental media. Thus, this study focuses on developing an environmentally dependable method for CB disposal. Littered CBs from filtered/electronic cigarettes were valorized into syngas (H2/CO). To seek a greener approach for the valorization of CBs, CO2 was intentionally considered as a reaction intermediate. Prior to multiple pyrolysis studies, the toxic chemicals in the CBs were qualitatively determined. This study experimentally proved that the toxic chemicals in CBs were detoxified/valorized into syngas. Furthermore, this work demonstrated that CO2 was effective in thermally destroying toxic chemicals in CBs via a gas-phase reaction. The reaction features and CO2 synergistically enhance syngas production. With the use of a supported Ni catalyst and CO2, syngas production from the catalytic pyrolysis of CBs was greatly enhanced (approximately 4 times). Finally, the gas-phase reaction by CO2 was reliably maintained owing to the synergistic mechanistic/reaction feature of CO2 for coke formation prevention on the catalyst surface.